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Small anion-assisted electrochemical potential splitting in a new series of bistriarylamine derivatives: organic mixed valency across a urea bridge and zwitterionization

We report the synthesis of a new bistriarylamine series having a urea bridge and investigate its mixed-valence (MV) states by electrochemical and spectroelectrochemical methods. We found that the supporting electrolytes had unusual effects on potential splitting during electrochemical behavior, in w...

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Detalles Bibliográficos
Autores principales: Tahara, Keishiro, Nakakita, Tetsufumi, Starikova, Alyona A, Ikeda, Takashi, Abe, Masaaki, Kikuchi, Jun-ichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6774064/
https://www.ncbi.nlm.nih.gov/pubmed/31598180
http://dx.doi.org/10.3762/bjoc.15.220