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Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study

Metal carbonyls are commonly employed probes for quantifying the donor properties of monodentate ligands. With a view to extending this methodology to mer‐tridentate “pincer” ligands, the spectroscopic properties [ν(CO), δ (13C), (1) J (RhC)] of rhodium(I) and rhodium(III) carbonyl complexes of the...

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Detalles Bibliográficos
Autores principales: Parker, Gemma L., Lau, Samantha, Leforestier, Baptiste, Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6774296/
https://www.ncbi.nlm.nih.gov/pubmed/31598095
http://dx.doi.org/10.1002/ejic.201900727