Spin Delocalization in the Radical Cations of Porphyrin Molecular Wires: A New Perspective on EPR Approaches

[Image: see text] The spin delocalization in the radical cations of a series of ethyne-linked oligoporphyrins was investigated using EPR spectroscopy. The room-temperature spectral envelope for these oligomers deviates significantly from the benchmark N(–0.5) trend in line width expected for a compl...

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Detalles Bibliográficos
Autores principales: Moise, Gabriel, Tejerina, Lara, Rickhaus, Michel, Anderson, Harry L., Timmel, Christiane R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6778911/
https://www.ncbi.nlm.nih.gov/pubmed/31512868
http://dx.doi.org/10.1021/acs.jpclett.9b02262

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6778911/
https://www.ncbi.nlm.nih.gov/pubmed/31512868
http://dx.doi.org/10.1021/acs.jpclett.9b02262

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