Mechanistic Insight into the Ring-Opening Polymerization of ε-Caprolactone and L-Lactide Using Ketiminate-Ligated Aluminum Catalysts

The reactivity and the reaction conditions of the ring-opening polymerization of ε-caprolactone (ε-CL) and L-lactide (LA) initiated by aluminum ketiminate complexes have been shown differently. Herein, we account for the observation by studying the mechanisms on the basis of density functional theor...

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Detalles Bibliográficos
Autores principales: Lin, Ya-Fan, Jheng, Nai-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6780811/
https://www.ncbi.nlm.nih.gov/pubmed/31546919
http://dx.doi.org/10.3390/polym11091530

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6780811/
https://www.ncbi.nlm.nih.gov/pubmed/31546919
http://dx.doi.org/10.3390/polym11091530

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