Cargando…

New Evidence of the Bidentate Binding Mode in 3-MBA Protected Gold Clusters: Analysis of Aqueous 13–18 kDa Gold-Thiolate Clusters by HPLC-ESI-MS Reveals Special Compositions Au(n)(3-MBA)(p), (n = 48–67, p = 26–30)

Gold clusters protected by 3-MBA ligands (MBA = mercaptobenzoic acid, –SPhCO(2)H) have attracted recent interest due to their unusual structures and their advantageous ligand-exchange and bioconjugation properties. Azubel et al. first determined the core structure of an Au(68)-complex, which was est...

Descripción completa

Detalles Bibliográficos
Autores principales: Black, David M., Hoque, M. Mozammel, Plascencia-Villa, Germán, Whetten, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6781097/
https://www.ncbi.nlm.nih.gov/pubmed/31514483
http://dx.doi.org/10.3390/nano9091303