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New Evidence of the Bidentate Binding Mode in 3-MBA Protected Gold Clusters: Analysis of Aqueous 13–18 kDa Gold-Thiolate Clusters by HPLC-ESI-MS Reveals Special Compositions Au(n)(3-MBA)(p), (n = 48–67, p = 26–30)
Gold clusters protected by 3-MBA ligands (MBA = mercaptobenzoic acid, –SPhCO(2)H) have attracted recent interest due to their unusual structures and their advantageous ligand-exchange and bioconjugation properties. Azubel et al. first determined the core structure of an Au(68)-complex, which was est...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6781097/ https://www.ncbi.nlm.nih.gov/pubmed/31514483 http://dx.doi.org/10.3390/nano9091303 |