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Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis

Azoxy bond is an important chemical bond and plays a crucial role in high energy density materials. However, the biosynthetic mechanism of azoxy bond remains enigmatic. Here we report that the azoxy bond biosynthesis of azoxymycins is an enzymatic and non-enzymatic coupling cascade reaction. In the...

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Detalles Bibliográficos
Autores principales: Guo, Yuan-Yang, Li, Zhen-Hua, Xia, Tian-Yu, Du, Yi-Ling, Mao, Xu-Ming, Li, Yong-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6783550/
https://www.ncbi.nlm.nih.gov/pubmed/31594923
http://dx.doi.org/10.1038/s41467-019-12250-1