Low-valent homobimetallic Rh complexes: influence of ligands on the structure and the intramolecular reactivity of Rh–H intermediates

Supporting two metal binding sites by a tailored polydentate trop-based (trop = 5H-dibenzo[a,d]cyclohepten-5-yl) ligand yields highly unsymmetric homobimetallic rhodium(i) complexes. Their reaction with hydrogen rapidly forms Rh hydrides that undergo an intramolecular semihydrogenation of two C[trip...

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Detalles Bibliográficos
Autores principales: Jurt, Pascal, Salnikov, Oleg G., Gianetti, Thomas L., Chukanov, Nikita V., Baker, Matthew G., Le Corre, Grégoire, Borger, Jaap E., Verel, Rene, Gauthier, Sébastien, Fuhr, Olaf, Kovtunov, Kirill V., Fedorov, Alexey, Fenske, Dieter, Koptyug, Igor V., Grützmacher, Hansjörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6788510/
https://www.ncbi.nlm.nih.gov/pubmed/31673319
http://dx.doi.org/10.1039/c9sc02683e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6788510/
https://www.ncbi.nlm.nih.gov/pubmed/31673319
http://dx.doi.org/10.1039/c9sc02683e

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