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Low-valent homobimetallic Rh complexes: influence of ligands on the structure and the intramolecular reactivity of Rh–H intermediates
Supporting two metal binding sites by a tailored polydentate trop-based (trop = 5H-dibenzo[a,d]cyclohepten-5-yl) ligand yields highly unsymmetric homobimetallic rhodium(i) complexes. Their reaction with hydrogen rapidly forms Rh hydrides that undergo an intramolecular semihydrogenation of two C[trip...
Autores principales: | Jurt, Pascal, Salnikov, Oleg G., Gianetti, Thomas L., Chukanov, Nikita V., Baker, Matthew G., Le Corre, Grégoire, Borger, Jaap E., Verel, Rene, Gauthier, Sébastien, Fuhr, Olaf, Kovtunov, Kirill V., Fedorov, Alexey, Fenske, Dieter, Koptyug, Igor V., Grützmacher, Hansjörg |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6788510/ https://www.ncbi.nlm.nih.gov/pubmed/31673319 http://dx.doi.org/10.1039/c9sc02683e |
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