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Zinc Substitution of Cobalt in Vitamin B(12): Zincobyric acid and Zincobalamin as Luminescent Structural B(12)‐Mimics
Replacing the central cobalt ion of vitamin B(12) by other metals has been a long‐held aspiration within the B(12)‐field. Herein, we describe the synthesis from hydrogenobyric acid of zincobyric acid (Znby) and zincobalamin (Znbl), the Zn‐analogues of the natural cobalt‐corrins cobyric acid and vita...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790578/ https://www.ncbi.nlm.nih.gov/pubmed/31420932 http://dx.doi.org/10.1002/anie.201908428 |