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Insight into D (6h) Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets

Following a novel synthetic strategy where the strong uniaxial ligand field generated by the Ph(3)SiO(−) (Ph(3)SiO(−)=anion of triphenylsilanol) and the 2,4‐di‐(t)Bu‐PhO(−) (2,4‐di‐(t)Bu‐PhO(−)=anion of 2,4‐di‐tertbutylphenol) ligands combined with the weak equatorial field of the ligand L(N6), lead...

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Detalles Bibliográficos
Autores principales: Canaj, Angelos B., Dey, Sourav, Martí, Emma Regincós, Wilson, Claire, Rajaraman, Gopalan, Murrie, Mark
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790654/
https://www.ncbi.nlm.nih.gov/pubmed/31343095
http://dx.doi.org/10.1002/anie.201907686