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A μ‐Phosphido Diiron Dumbbell in Multiple Oxidation States

The reaction of the ferrous complex [LFe(NCMe)(2)](OTf)(2) (1), which contains a macrocyclic tetracarbene as ligand (L), with Na(OCP) generates the OCP(−)‐ligated complex [LFe(PCO)(CO)]OTf (2) together with the dinuclear μ‐phosphido complex [(LFe)(2)P](OTf)(3) (3), which features an unprecedented li...

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Detalles Bibliográficos
Autores principales: Ghosh, Munmun, Cramer, Hanna H., Dechert, Sebastian, Demeshko, Serhiy, John, Michael, Hansmann, Max M., Ye, Shengfa, Meyer, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790664/
https://www.ncbi.nlm.nih.gov/pubmed/31350785
http://dx.doi.org/10.1002/anie.201908213