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A μ‐Phosphido Diiron Dumbbell in Multiple Oxidation States
The reaction of the ferrous complex [LFe(NCMe)(2)](OTf)(2) (1), which contains a macrocyclic tetracarbene as ligand (L), with Na(OCP) generates the OCP(−)‐ligated complex [LFe(PCO)(CO)]OTf (2) together with the dinuclear μ‐phosphido complex [(LFe)(2)P](OTf)(3) (3), which features an unprecedented li...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790664/ https://www.ncbi.nlm.nih.gov/pubmed/31350785 http://dx.doi.org/10.1002/anie.201908213 |