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Generation and Applications of the Hydroxide Trihydrate Anion, [OH(OH(2))(3)](−), Stabilized by a Weakly Coordinating Cation
The reaction of a strongly basic phosphazene (Schwesinger base) with water afforded the corresponding metastable hydroxide trihydrate [OH(OH(2))(3)](−) salt. This is the first hydroxide solvate that is not in contact with a cation and furthermore one of rare known water‐stabilized hydroxide anions....
Autores principales: | Weitkamp, Robin F., Neumann, Beate, Stammler, Hans‐Georg, Hoge, Berthold |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790940/ https://www.ncbi.nlm.nih.gov/pubmed/31373109 http://dx.doi.org/10.1002/anie.201908589 |
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