Quadruple bonding between iron and boron in the BFe(CO)(3)(−) complex

While main group elements have four valence orbitals accessible for bonding, quadruple bonding to main group elements is extremely rare. Here we report that main group element boron is able to form quadruple bonding interactions with iron in the BFe(CO)(3)(-) anion complex, which has been revealed b...

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Detalles Bibliográficos
Autores principales: Chi, Chaoxian, Wang, Jia-Qi, Hu, Han-Shi, Zhang, Yang-Yang, Li, Wan-Lu, Meng, Luyan, Luo, Mingbiao, Zhou, Mingfei, Li, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6797760/
https://www.ncbi.nlm.nih.gov/pubmed/31624260
http://dx.doi.org/10.1038/s41467-019-12767-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6797760/
https://www.ncbi.nlm.nih.gov/pubmed/31624260
http://dx.doi.org/10.1038/s41467-019-12767-5

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