Site Selectivity in Pd-Catalyzed Reactions of α-Diazo-α-(methoxycarbonyl)acetamides: Effects of Catalysts and Substrate Substitution in the Synthesis of Oxindoles and β-Lactams

The Pd-catalyzed intramolecular carbene C–H insertion of α-diazo-α-(methoxycarbonyl)acetamides to prepare oxindoles as well as β-lactams was studied. In order to identify what factors influence the selectivity of the processes, we explored how the reactions are affected by the catalyst type, using t...

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Detalles Bibliográficos
Autores principales: Solé, Daniel, Pérez-Janer, Ferran, Amenta, Arianna, Bennasar, M.-Lluïsa, Fernández, Israel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6803982/
https://www.ncbi.nlm.nih.gov/pubmed/31575030
http://dx.doi.org/10.3390/molecules24193551

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6803982/
https://www.ncbi.nlm.nih.gov/pubmed/31575030
http://dx.doi.org/10.3390/molecules24193551

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