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Chemoenzymatic Total Synthesis of (+)-10-Keto-Oxycodone from Phenethyl Acetate †
The total synthesis of (+)-10-keto-oxycodone was attained from phenethyl acetate in a stereoselective manner. Absolute stereochemistry was established via enzymatic dihydroxylation of phenethyl acetate with the recombinant strain JM109 (pDTG601A) that furnished the corresponding cis-cyclohexadienedi...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804203/ https://www.ncbi.nlm.nih.gov/pubmed/31557873 http://dx.doi.org/10.3390/molecules24193477 |