Unexpected Molecular Structure of a Putative Rhenium‐Dioxo‐Benzocarbaporphyrin Complex. Implications for the Highest Transition Metal Valence in a Porphyrin‐Type Ligand Environment

A combination of quantum chemical calculations and synthetic studies was used to address the possibility of very high (>6) valence states of transition metals in porphyrin‐type complexes. With corrole as a supporting ligand, DFT calculations ruled out Re(VII) and Ir(VII) dioxo complexes as stable...

Descripción completa

Detalles Bibliográficos
Autores principales: Alemayehu, Abraham B., Vazquez‐Lima, Hugo, Teat, Simon J., Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804418/
https://www.ncbi.nlm.nih.gov/pubmed/31649839
http://dx.doi.org/10.1002/open.201900271

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804418/
https://www.ncbi.nlm.nih.gov/pubmed/31649839
http://dx.doi.org/10.1002/open.201900271

Ejemplares similares