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Ligand Structure Effects on Molecular Assembly and Magnetic Properties of Copper(II) Complexes with 3-Pyridyl-Substituted Nitronyl Nitroxide Derivatives

[Image: see text] Reaction of Cu(hfac)(2) with methyl- and bromo-3-pyridyl-substituted nitronyl nitroxides (L(R)) leads to assemble a diverse set of coordination complexes: mononuclear [Cu(hfac)(2)L(2-Me)], binuclear [{Cu(hfac)(2)}(2)(H(2)O)L(2-Me)], trinuclear [{Cu(hfac)(2)}(3)(L(6-Br))(2)], pentan...

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Detalles Bibliográficos
Autores principales: Sherstobitova, Tatiana, Maryunina, Kseniya, Tolstikov, Svyatoslav, Letyagin, Gleb, Romanenko, Galina, Nishihara, Sadafumi, Inoue, Katsuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6811855/
https://www.ncbi.nlm.nih.gov/pubmed/31656889
http://dx.doi.org/10.1021/acsomega.9b01575