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Unraveling the thermodynamic criteria for size-dependent spontaneous phase separation in soft porous crystals

Soft porous crystals (SPCs) harbor a great potential as functional nanoporous materials owing to their stimuli-induced and tuneable morphing between different crystalline phases. These large-amplitude phase transitions are often assumed to occur cooperatively throughout the whole material, which the...

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Detalles Bibliográficos
Autores principales: Rogge, Sven M. J., Waroquier, Michel, Van Speybroeck, Veronique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6813293/
https://www.ncbi.nlm.nih.gov/pubmed/31649249
http://dx.doi.org/10.1038/s41467-019-12754-w