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A merged copper(I/II) cluster isolated from Glaser coupling
Ubiquitous copper-oxygen species are pivotal in enabling multifarious oxidation reactions in biological and chemical transformations. We herein construct a macrocycle-protected mixed-valence cluster [((t)BuC≡CCu(I)(3))-(μ(2)-OH)-Cu(II)] by merging a copper acetylide cluster with a copper-oxygen moie...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6813345/ https://www.ncbi.nlm.nih.gov/pubmed/31649254 http://dx.doi.org/10.1038/s41467-019-12889-w |