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Aerobic Oxidation of Benzylic Carbons Using a Guanidine Base
[Image: see text] Metal-free reaction conditions featuring oxygen and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) were employed for the selective oxidation of benzyl amines and active methylene compounds to afford various amides and ketones. Owing to the strong basicity of guanidine bases, TBD is pres...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6822219/ https://www.ncbi.nlm.nih.gov/pubmed/31681903 http://dx.doi.org/10.1021/acsomega.9b03064 |