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Unexpected reactions of NHC*—Cu(I) and —Ag(I) bromides with potassium thio- or seleno­cyanate

The reactions of N-heterocyclic carbene Cu(I) and Ag(I) halides with potassium thio- or seleno­cyanate gave unexpected products. The attempted substitution reaction of bromido­(1,3-dibenzyl-4,5-di­phenyl­imidazol-2-yl­idene)silver (NHC*—Ag—Br) with KSCN yielded bis­[bis­(1,3-dibenzyl-4,5-di­phenyl­i...

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Detalles Bibliográficos
Autores principales: Tacke, Matthias, Marhöfer, Daniel, Althani, Hessah, Müller-Bunz, Helge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6829722/
https://www.ncbi.nlm.nih.gov/pubmed/31709086
http://dx.doi.org/10.1107/S2056989019013719