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The ‘super acid’ BF(3)H(2)O stabilized by 1,4-dioxane: new preparative aspects and the crystal structure of BF(3)H(2)O·C(4)H(8)O(2)

Highly Brønsted-acidic boron trifluoride monohydrate, a widely used ‘super acid-catalyst’, is a colourless fuming liquid that releases BF(3) at room temperature. Com­pared to the liquid com­ponents, i.e. boron trifluoride monohydrate and 1,4-dioxane, their 1:1 adduct, BF(3)H(2)O·C(4)H(8)O(2), is a s...

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Detalles Bibliográficos
Autores principales: Barthen, Peter, Frank, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6829742/
https://www.ncbi.nlm.nih.gov/pubmed/31709109
http://dx.doi.org/10.1107/S2056989019014312