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The ‘super acid’ BF(3)H(2)O stabilized by 1,4-dioxane: new preparative aspects and the crystal structure of BF(3)H(2)O·C(4)H(8)O(2)
Highly Brønsted-acidic boron trifluoride monohydrate, a widely used ‘super acid-catalyst’, is a colourless fuming liquid that releases BF(3) at room temperature. Compared to the liquid components, i.e. boron trifluoride monohydrate and 1,4-dioxane, their 1:1 adduct, BF(3)H(2)O·C(4)H(8)O(2), is a s...
Autores principales: | Barthen, Peter, Frank, Walter |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6829742/ https://www.ncbi.nlm.nih.gov/pubmed/31709109 http://dx.doi.org/10.1107/S2056989019014312 |
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