Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

The conventional oxidative Heck reaction between aryl boronic acids and alkenes typically involved the Pd(II)/Pd(0)/Pd(II) catalytic cycle incorporating an external oxidant and often suffered C=C bond isomerization for internal alkyl-substituted alkenes via chain-walking. Herein, we demonstrate that...

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Detalles Bibliográficos
Autores principales: Lv, Honggui, Kang, Huiying, Zhou, Biying, Xue, Xiaosong, Engle, Keary M., Zhao, Dongbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6831602/
https://www.ncbi.nlm.nih.gov/pubmed/31690717
http://dx.doi.org/10.1038/s41467-019-12949-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6831602/
https://www.ncbi.nlm.nih.gov/pubmed/31690717
http://dx.doi.org/10.1038/s41467-019-12949-1

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