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Insertion of Carbenes into Deprotonated nido-Undecaborane, B(11)H(13)(2-)
We have examined the insertion of carbenes carrying leaving groups into the [nido-B(11)H(13)](2−) dianion to form the [closo-1-CB(11)H(12)](−) anion. The best procedure uses CF(3)SiMe(3) and LiCl as the source of CF(2). It is simple, convenient and scalable and proceeds with 70–90% yield. Density fu...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6833071/ https://www.ncbi.nlm.nih.gov/pubmed/31640159 http://dx.doi.org/10.3390/molecules24203779 |