Oxygen atom transfer with organofunctionalized polyoxovanadium clusters: O-atom vacancy formation with tertiary phosphanes and deoxygenation of styrene oxide

We report a rare example of oxygen atom transfer (OAT) from a polyoxometalate cluster to a series of tertiary phosphanes. Addition of PR(3) (PR(3) = PMe(3), PMe(2)Ph, PMePh(2), PPh(3)) to a neutral methoxide-bridged polyoxovanadate-alkoxide (POV-alkoxide) cluster, [V(6)O(7)(OMe)(12)](0), results in...

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Detalles Bibliográficos
Autores principales: Petel, Brittney E., Meyer, Rachel L., Brennessel, William W., Matson, Ellen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6837047/
https://www.ncbi.nlm.nih.gov/pubmed/31853359
http://dx.doi.org/10.1039/c9sc02882j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6837047/
https://www.ncbi.nlm.nih.gov/pubmed/31853359
http://dx.doi.org/10.1039/c9sc02882j

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