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Diarylamine/diarylnitroxide cycle: quantum chemical and electrochemical estimation

Possibility for diarylamine/diarylnitroxide cycling via electrochemical N–O bond formation/bond breaking processes was considered using quantum-chemical and electrochemical methods. It was shown that electrochemically reduced diarylnitroxides undergo fast N–O bond cleavage in the presence of oxophil...

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Detalles Bibliográficos
Autores principales: Levitskiy, Oleg A., Sentyurin, Vyacheslav V., Magdesieva, Tatiana V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6838958/
https://www.ncbi.nlm.nih.gov/pubmed/31720473
http://dx.doi.org/10.1016/j.heliyon.2019.e02735