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A selective route to aryl-triphosphiranes and their titanocene-induced fragmentation

Triphosphiranes are three-membered phosphorus cycles and their fundamental reactivity has been studied in recent decades. We recently developed a high-yielding, selective synthesis for various aryl-substituted triphosphiranes. Variation of the reaction conditions in combination with theoretical stud...

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Detalles Bibliográficos
Autores principales: Schumann, André, Reiß, Fabian, Jiao, Haijun, Rabeah, Jabor, Siewert, Jan-Erik, Krummenacher, Ivo, Braunschweig, Holger, Hering-Junghans, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6839504/
https://www.ncbi.nlm.nih.gov/pubmed/31853345
http://dx.doi.org/10.1039/c9sc02322d