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Magnesium hydride alkene insertion and catalytic hydrosilylation
The dimeric β-diketiminato magnesium hydride, [(BDI)MgH](2), reacts at 80 °C with the terminal alkenes, 1-hexene, 1-octene, 3-phenyl-1-propene and 3,3-dimethyl-butene to provide the respective n-hexyl, n-octyl, 3-phenylpropyl and 3,3-dimethyl-butyl magnesium organometallics. The facility for and the...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6839609/ https://www.ncbi.nlm.nih.gov/pubmed/31814958 http://dx.doi.org/10.1039/c9sc02056j |