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Magnesium hydride alkene insertion and catalytic hydrosilylation

The dimeric β-diketiminato magnesium hydride, [(BDI)MgH](2), reacts at 80 °C with the terminal alkenes, 1-hexene, 1-octene, 3-phenyl-1-propene and 3,3-dimethyl-butene to provide the respective n-hexyl, n-octyl, 3-phenylpropyl and 3,3-dimethyl-butyl magnesium organometallics. The facility for and the...

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Detalles Bibliográficos
Autores principales:	Garcia, Lucia, Dinoi, Chiara, Mahon, Mary F., Maron, Laurent, Hill, Michael S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6839609/ https://www.ncbi.nlm.nih.gov/pubmed/31814958 http://dx.doi.org/10.1039/c9sc02056j

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