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B(C(6)F(5))(3)-catalyzed dehydrogenative cyclization of N-tosylhydrazones and anilines via a Lewis adduct: a combined experimental and computational investigation

Tris(pentafluorophenyl)borane-catalyzed dehydrogenative-cyclization of N-tosylhydrazones with aromatic amines has been disclosed. This metal-free catalytic protocol is compatible with a range of functional groups to provide both symmetrical and unsymmetrical 3,4,5-triaryl-1,2,4-triazoles. Mechanisti...

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Detalles Bibliográficos
Autores principales: Guru, Murali Mohan, De, Sriman, Dutta, Sayan, Koley, Debasis, Maji, Biplab
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6839809/
https://www.ncbi.nlm.nih.gov/pubmed/31853352
http://dx.doi.org/10.1039/c9sc02492a