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Redox-neutral ortho-C–H amination of pinacol arylborates via palladium(ii)/norbornene catalysis for aniline synthesis

A palladium(ii)/norbornene cooperative catalysis enabled redox-neutral ortho-C–H amination of pinacol aryl- or heteroarylborates for the synthesis of structurally diverse anilines is reported. This method is scalable, robust (tolerance of air and moisture), phosphine ligand-free, and compatible with...

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Detalles Bibliográficos
Autores principales: Chen, Shuqing, Wang, Peng, Cheng, Hong-Gang, Yang, Chihui, Zhou, Qianghui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6839810/
https://www.ncbi.nlm.nih.gov/pubmed/31803416
http://dx.doi.org/10.1039/c9sc02759a