Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles

Great efforts have been made in the activation of a C(alkenyl)-H bond vicinal to the directing group to proceed via five- or six-membered endo-metallocycles. In stark contrast, functionalization of a C(alkenyl)-H bond geminal to the directing group via exo-metallocycle pathway continued to be elusiv...

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Detalles Bibliográficos
Autores principales: Meng, Keke, Li, Tingyan, Yu, Chunbing, Shen, Cong, Zhang, Jian, Zhong, Guofu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6841671/
https://www.ncbi.nlm.nih.gov/pubmed/31704916
http://dx.doi.org/10.1038/s41467-019-13098-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6841671/
https://www.ncbi.nlm.nih.gov/pubmed/31704916
http://dx.doi.org/10.1038/s41467-019-13098-1

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