Oxidant speciation and anionic ligand effects in the gold-catalyzed oxidative coupling of arenes and alkynes

The mechanism of the gold-catalyzed oxidative cross-coupling of arenes and alkynes has been studied in detail combining stoichiometric experiments with putative reaction intermediates and DFT calculations. Our data suggest that ligand exchange between the alkyne, the Au(i)-catalyst and the hypervale...

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Detalles Bibliográficos
Autores principales: Hofer, Manuel, de Haro, Teresa, Gómez-Bengoa, Enrique, Genoux, Alexandre, Nevado, Cristina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6844217/
https://www.ncbi.nlm.nih.gov/pubmed/31803420
http://dx.doi.org/10.1039/c9sc02372k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6844217/
https://www.ncbi.nlm.nih.gov/pubmed/31803420
http://dx.doi.org/10.1039/c9sc02372k

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