Gold(I)-Catalyzed Aromatization: Expeditious Synthesis of Polyfunctionalized Naphthalenes

A gold-catalyzed 6-endo-dig carbocyclization of alkyne with the pendent diazo group is reported. It provides an expeditious approach for the synthesis of multi-functionalized naphthalene derivatives under mild conditions. Mechanistic studies suggest that a vinyl gold carbene is generated as the key...

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Detalles Bibliográficos
Autores principales: Zhang, Cheng, Hong, Kemiao, Dong, Shanliang, Pei, Chao, Zhang, Xiaolu, He, Ciwang, Hu, Wenhao, Xu, Xinfang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6849331/
https://www.ncbi.nlm.nih.gov/pubmed/31710965
http://dx.doi.org/10.1016/j.isci.2019.10.042

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6849331/
https://www.ncbi.nlm.nih.gov/pubmed/31710965
http://dx.doi.org/10.1016/j.isci.2019.10.042

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