New Insights in Frustrated Lewis Pair Chemistry with Azides

The geminal frustrated Lewis pair (FLP) tBu(2)PCH(2)BPh(2) (1) reacts with phenyl‐, mesityl‐, and tert‐butyl azide affording, respectively, six, five, and four‐membered rings as isolable products. DFT calculations revealed that the formation of all products proceeds via the six‐membered ring structu...

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Detalles Bibliográficos
Autores principales: Boom, Devin H. A., Jupp, Andrew R., Nieger, Martin, Ehlers, Andreas W., Slootweg, J. Chris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6851766/
https://www.ncbi.nlm.nih.gov/pubmed/31497899
http://dx.doi.org/10.1002/chem.201902710

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6851766/
https://www.ncbi.nlm.nih.gov/pubmed/31497899
http://dx.doi.org/10.1002/chem.201902710

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