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Flavinium Catalysed Photooxidation: Detection and Characterization of Elusive Peroxyflavinium Intermediates
Flavin‐based catalysts are photoactive in the visible range which makes them useful in biology and chemistry. Herein, we present electrospray‐ionization mass‐spectrometry detection of short‐lived intermediates in photooxidation of toluene catalysed by flavinium ions (Fl(+)). Previous studies have sh...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6852162/ https://www.ncbi.nlm.nih.gov/pubmed/31364790 http://dx.doi.org/10.1002/anie.201906293 |