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Flavinium Catalysed Photooxidation: Detection and Characterization of Elusive Peroxyflavinium Intermediates

Flavin‐based catalysts are photoactive in the visible range which makes them useful in biology and chemistry. Herein, we present electrospray‐ionization mass‐spectrometry detection of short‐lived intermediates in photooxidation of toluene catalysed by flavinium ions (Fl(+)). Previous studies have sh...

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Detalles Bibliográficos
Autores principales: Zelenka, Jan, Cibulka, Radek, Roithová, Jana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6852162/
https://www.ncbi.nlm.nih.gov/pubmed/31364790
http://dx.doi.org/10.1002/anie.201906293