Merging Regiodivergent Catalysis with Atom‐Economical Radical Arylation

A titanocene‐catalyzed regiodivergent radical arylation is described that allows access to either enantiomerically pure tetrahydroquinolines or indolines from a common starting material. The regioselectivity of epoxide opening that results in the high selectivity of heterocycle formation is controll...

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Detalles Bibliográficos
Autores principales: Mühlhaus, Felix, Weißbarth, Hendrik, Dahmen, Tobias, Schnakenburg, Gregor, Gansäuer, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6852184/
https://www.ncbi.nlm.nih.gov/pubmed/31394024
http://dx.doi.org/10.1002/anie.201908860

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6852184/
https://www.ncbi.nlm.nih.gov/pubmed/31394024
http://dx.doi.org/10.1002/anie.201908860

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