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Gold(I) Complexes Stabilized by Nine‐ and Ten‐Membered N‐Heterocyclic Carbene Ligands

Nine‐ and ten‐membered N‐heterocyclic carbene (NHC) ligands have been developed and for the first time their gold(I) complexes were synthesized. The protonated NHC pro‐ligands 2 a–h were prepared by the reaction of readily available N,N′‐diarylformamidines with bis‐electrophilic building blocks, fol...

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Detalles Bibliográficos
Autores principales: Cervantes‐Reyes, Alejandro, Rominger, Frank, Rudolph, Matthias, Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6852534/
https://www.ncbi.nlm.nih.gov/pubmed/31310385
http://dx.doi.org/10.1002/chem.201902458