Controlled chemoselective defluorination and non-defluorination for [5 + 1] aromatic annulation via Meisenheimer-type nitrogen anion and radical intermediates

Reported is a unique chemoselectivity approach to base-promoted defluorinative and Cu(i)-catalyzed aerobic oxidative non-defluorinative [5 + 1] condensation aromatizations of simple unsaturated ketones with ammonium salts via Meisenheimer-type nitrogen anion and radical intermediates. The CuBr/O(2)...

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Detalles Bibliográficos
Autores principales: Qian, Jinlong, Zhang, Jinlong, Yang, Huameng, Kang, Lei, Jiang, Gaoxi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6853080/
https://www.ncbi.nlm.nih.gov/pubmed/31803454
http://dx.doi.org/10.1039/c9sc03216a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6853080/
https://www.ncbi.nlm.nih.gov/pubmed/31803454
http://dx.doi.org/10.1039/c9sc03216a

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