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Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands
Molecular uranium nitride complexes were prepared to relate their small molecule reactivity to the nature of the U[double bond, length as m-dash]N[double bond, length as m-dash]U bonding imposed by the supporting ligand. The U(4+)–U(4+) nitride complexes, [NBu(4)][{(((t)BuO)(3)SiO)(3)U}(2)(μ-N)], [N...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6853081/ https://www.ncbi.nlm.nih.gov/pubmed/31803458 http://dx.doi.org/10.1039/c9sc02149c |