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Pd-catalyzed site-selective C(sp(2))–H radical acylation of phenylalanine containing peptides with aldehydes
The site-selective functionalization of C–H bonds within a peptide framework remains a challenging task of prime synthetic importance. Herein, the first Pd-catalyzed δ-C(sp(2))–H acylation of Phe containing peptides with aldehydes is described. This oxidative coupling is distinguished by its site-sp...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6853082/ https://www.ncbi.nlm.nih.gov/pubmed/31803461 http://dx.doi.org/10.1039/c9sc03425k |