Picosecond to millisecond tracking of a photocatalytic decarboxylation reaction provides direct mechanistic insights

The photochemical decarboxylation of carboxylic acids is a versatile route to free radical intermediates for chemical synthesis. However, the sequential nature of this multi-step reaction renders the mechanism challenging to probe. Here, we employ a 100 kHz mid-infrared probe in a transient absorpti...

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Detalles Bibliográficos
Autores principales: Bhattacherjee, Aditi, Sneha, Mahima, Lewis-Borrell, Luke, Tau, Omri, Clark, Ian P., Orr-Ewing, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6853971/
https://www.ncbi.nlm.nih.gov/pubmed/31723133
http://dx.doi.org/10.1038/s41467-019-13154-w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6853971/
https://www.ncbi.nlm.nih.gov/pubmed/31723133
http://dx.doi.org/10.1038/s41467-019-13154-w

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