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Picosecond to millisecond tracking of a photocatalytic decarboxylation reaction provides direct mechanistic insights
The photochemical decarboxylation of carboxylic acids is a versatile route to free radical intermediates for chemical synthesis. However, the sequential nature of this multi-step reaction renders the mechanism challenging to probe. Here, we employ a 100 kHz mid-infrared probe in a transient absorpti...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6853971/ https://www.ncbi.nlm.nih.gov/pubmed/31723133 http://dx.doi.org/10.1038/s41467-019-13154-w |