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Base Mediated Tandem Vinylogous Addition and Cyclization of γ-Phosphonyl/Sulfonyl Crotonates and Ynones: Synthesis of Functionalized 2-Pyrones

[Image: see text] A general method for highly functionalized 2-pyrones via a base-mediated sequential vinylogous addition and cyclization of γ-phosphonyl/sulfonyl crotonates and ynones are described. An exclusive E-geometry with respect to the newly generated olefin substituent at C3 of pyrone was o...

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Detalles Bibliográficos
Autores principales: Parameshwar, Matam, Rajesh, Manda, Balasubramanian, Sridhar, Sridhar Reddy, Maddi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6854826/
https://www.ncbi.nlm.nih.gov/pubmed/31737846
http://dx.doi.org/10.1021/acsomega.9b02874