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Template catalysis by manganese pincer complexes: oxa- and aza-Michael additions to unsaturated nitriles
Activation of C[triple bond, length as m-dash]N bonds by metal–ligand cooperation provides a new route for the functionalization of nitriles. Herein, we report the electrophilic activation of unsaturated nitriles by dearomatized manganese pincer complexes for the oxa- and aza-Michael addition reacti...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6855260/ https://www.ncbi.nlm.nih.gov/pubmed/31762979 http://dx.doi.org/10.1039/c9sc03269j |