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Rhodium(I) Pincer Complexes of Nitrous Oxide

The synthesis of two well‐defined rhodium(I) complexes of nitrous oxide (N(2)O) is reported. These normally elusive adducts are stable in the solid state and persist in solution at ambient temperature, enabling comprehensive structural interrogation by (15)N NMR and IR spectroscopy, and single‐cryst...

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Detalles Bibliográficos
Autores principales: Gyton, Matthew R., Leforestier, Baptiste, Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856677/
https://www.ncbi.nlm.nih.gov/pubmed/31513331
http://dx.doi.org/10.1002/anie.201908333