Facile C=O Bond Splitting of Carbon Dioxide Induced by Metal–Ligand Cooperativity in a Phosphinine Iron(0) Complex

New iron complexes [Cp*FeL](−) (1‐σ and 1‐π, Cp*=C(5)Me(5)) containing the chelating phosphinine ligand 2‐(2′‐pyridyl)‐4,6‐diphenylphosphinine (L) have been prepared, and found to undergo facile reaction with CO(2) under ambient conditions. The outcome of this reaction depends on the coordination mo...

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Detalles Bibliográficos
Autores principales: Leitl, Julia, Marquardt, Michael, Coburger, Peter, Scott, Daniel J., Streitferdt, Verena, Gschwind, Ruth M., Müller, Christian, Wolf, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856682/
https://www.ncbi.nlm.nih.gov/pubmed/31441566
http://dx.doi.org/10.1002/anie.201909240

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856682/
https://www.ncbi.nlm.nih.gov/pubmed/31441566
http://dx.doi.org/10.1002/anie.201909240

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