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Magnesium Cyanide or Isocyanide?
Preference for the binding mode of the CN(−) ligand to Mg (Mg−CN vs. Mg−NC) is investigated. A monomeric Mg complex with a terminal CN ligand was prepared using the dipyrromethene ligand (Mes)DPM which successfully blocks dimerization. While reaction of ((Mes)DPM)MgN(SiMe(3))(2) with Me(3)SiCN gave...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856803/ https://www.ncbi.nlm.nih.gov/pubmed/31461208 http://dx.doi.org/10.1002/anie.201909511 |